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蒸汽密度
2 (vs air)
蒸汽壓力
14.39 psi ( 55 °C)
184 mmHg ( 20 °C)
3.67 psi ( 20 °C)
同位素純度
99.9 atom % D
化驗
≥99% (CP)
形狀
liquid
包含
1 % (v/v) TMS
expl. lim.
13.2 %
包裝
ampule of 10 g
glass bottle of 25 g, 50 g
技術
GC/MS: suitable
NMR: suitable
雜質
≤0.0500% water
water
折射率
n20/D 1.355 (lit.)
bp
55.5 °C (lit.)
mp
−93.8 °C (lit.)
密度
0.872 g/mL at 25 °C (lit.)
質量偏移
M+6
SMILES 字串
[2H]C([2H])([2H])C(=O)C([2H])([2H])[2H]
InChI
1S/C3H6O/c1-3(2)4/h1-2H3/i1D3,2D3
InChI 密鑰
CSCPPACGZOOCGX-WFGJKAKNSA-N
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一般說明
Acetone-d6 is a deuterated NMR solvent containing 1% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. The Infrared and Raman spectra of acetone-d6 have been analyzed. Pyrolysis and photolysis of acetone-d6 and methane mixtures have been investigated as a function of temperature. It has been reported to be prepared by reacting heavy water with propyne-d4 in the presence of mercury catalyst.
應用
Acetone-d6 may be used as an internal standard to detect aldehydes and acetone in water by headspace-solid-phase microextraction and gas chromatography-mass spectrometry.
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訊號詞
Danger
危險聲明
危險分類
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
-2.2 °F - closed cup
閃點(°C)
-19 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves
The Pyrolysis and Photolysis of Acetone-d6 in the Presence of Methane.
Journal of the American Chemical Society, 76(16), 4196-4198 (1954)
Journal of separation science, 34(6), 693-699 (2011-02-15)
We describe a simple and automatic method to determine nine aldehydes and acetone simultaneously in water. This method is based on derivatization with 2,2,2-trifluoroethylhydrazine (TFEH) and consecutive headspace-solid-phase microextraction and gas chromatography-mass spectrometry. Acetone-d(6) was used as the internal standard.
Vibrational spectra and assignment of acetone, ααα acetone-d3 and acetone-d6.
Spectrochimica Acta Part A: Molecular Spectroscopy, 22(4), 593-614 (1966)
Neue Synthese von Aceton-d6.
Helvetica Chimica Acta, 45(1), 59-62 (1962)
Bioorganic & medicinal chemistry, 22(23), 6564-6569 (2014-12-03)
A series of 3-nitrochalcones have been synthesized enroute towards fused ring pyrazolones and isoxazolones. Base catalyzed condensation of the chalcones with ethylacetoacetate yielded cyclohexenones in good yields (74-76%). The treatment of cyclohexenones with hydrazine hydrate or hydroxylamine chloride in the
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