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Merck

359297

Sigma-Aldrich

乙硫代硫酸钠

technical grade, 80%

别名:

乙基硫醇 钠盐, 乙硫醇 钠盐

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About This Item

线性分子式:
CH3CH2SNa
CAS号:
分子量:
84.12
Beilstein:
3593647
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

化驗

80%

SMILES 字串

CCS[Na]

InChI

1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1

InChI 密鑰

QJDUDPQVDAASMV-UHFFFAOYSA-M

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一般說明

本文研究了 FeCl 2 或 FeCl 3 与乙硫代硫酸钠在 N -甲基甲酰胺 (NMF) 中的反应。研究了乙硫代硫酸钠与取代 1,2-二硫戊环-3-硫酮的反应。

應用

乙硫代硫酸钠可用于 G-25 凝胶过滤 (ox)-状态 FeMo 辅因子 \ [FeMoco (ox)](来自 棕色固氮菌 固氮酶)的 N -甲基甲酰胺的平衡滴定。它可用于合成一系列混合化合物,这些化合物结合了维生素 E 的药效氧化还原部分和负责 I 类抗心律失常药普鲁卡因胺和利多卡因的抗心律失常特性的关键特征。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Patrick Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 10(4), 373-382 (2005-05-03)
The reaction of FeCl(2) or FeCl(3) with sodium ethanethiolate (SEt) in N-methylformamide (NMF) has been reevaluated to rectify a previous Fe(II) oxidation artifact. On titrating Fe(II) with EtS(-) concentrations up to 12 mol Eq, new features in the UV/vis spectrum
Maria Koufaki et al.
Bioorganic & medicinal chemistry, 11(23), 5209-5219 (2003-11-08)
We have synthesized a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine. Procainamide analogue (2a) and lidocaine analogues (14a) and
P Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 6(7), 683-697 (2001-10-30)
Equilibrium titrations in N-methylformamide (NMF) of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase were carried out using sodium ethanethiolate and followed using UV/Vis absorption spectroscopy. For Fe-Moco(ox), a non-linear least squares (NLLSQ) fit to the data
Reactivity of substituted 1, 2-dithiole-3-thiones with sodium ethanethiolate: a convenient route to a novel heterocycle.
Largeron M, et al.
Tetrahedron, 43(15), 3421-3428 (1987)
Piotr Borowski et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 86, 571-585 (2011-12-14)
Multi-parameter scaling techniques, such as Scaled Quantum Mechanical (SQM) force field [J. Am. Chem. Soc. 105 (1983) 7037-7047; J. Phys. Chem. A 102 (1998) 1412-1424] or Effective Scaling Frequency Factor (ESFF) [Chem. Phys. Lett. 446 (2007) 191-198; J. Mol. Spectrosc.

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