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化驗
99%
光學活性
[α]25/D −168°, c = 2 in chloroform
光學純度
ee: 99% (HPLC)
mp
121-123 °C (lit.)
SMILES 字串
C[C@@H]1NC(=O)O[C@@H]1c2ccccc2
InChI
1S/C10H11NO2/c1-7-9(13-10(12)11-7)8-5-3-2-4-6-8/h2-7,9H,1H3,(H,11,12)/t7-,9-/m0/s1
InChI 密鑰
PPIBJOQGAJBQDF-CBAPKCEASA-N
應用
用于不对称合成的多功能手性助剂。综述请查阅 Aldrichimica Acta。
(4S,5R)-(-)-4-Methyl-5-phenyl-2-oxazolidinone may be used to synthesize (4S,5R)-N-tert-butyloxycarbonyl)-4-methyl-5-carboxy-2-oxazolidinone and (+)-pumiliotoxin B.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Efficient Total Syntheses of Pumiliotoxins A and B. Applications of Iodide-Promoted Iminium Ion- Alkyne Cyclizations in Alkaloid Construction.
Journal of the American Chemical Society, 118(38), 9062-9072 (1996)
Antibody catalysis of peptidyl-prolyl cis-trans isomerization in the folding of RNase T1.
Proceedings of the National Academy of Sciences of the USA, 95(13), 7251-7256 (1998)
Aldrichimica Acta, 30, 3-3 (1997)
Chromatograms
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