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About This Item
线性分子式:
CH3(CH2)3Li
CAS号:
分子量:
64.06
Beilstein:
1209227
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
推荐产品
形狀
liquid
儲存期限
limited shelf life
濃度
2.7 M in heptane
顏色
yellow
密度
0.71 g/mL at 20 °C
儲存溫度
2-8°C
SMILES 字串
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI 密鑰
MZRVEZGGRBJDDB-UHFFFAOYSA-N
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應用
n-Butyllithium is a strong nucleophile in the synthetic organic chemistry. It is also used as an initiator in the polymerization process.
注意
长时间储存可形成氢化锂沉淀
訊號詞
Danger
危險分類
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 2
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Methylsulfinyl carbanion (CH3-SO-CH2-). Formation and applications to organic synthesis
Corey EJ and Chaykovsky M
Journal of the American Chemical Society, 87(6), 1345-1353 (1965)
Some trends observed in [60] fullerene polymerization activated by butyllithium isomers
Atovmyan EG, et al.
Russian Chemical Bulletin, 61(11), 2178-2179 (2012)
Tatiana Guzzo et al.
Biomolecules, 10(11) (2020-10-30)
The stability and the degradation of polymers in physiological conditions are very important issues in biomedical applications. The copolymer of hyaluronic acid and poly-D,L-lactic acid (made available in a product called DAC®) produces a hydrogel which retains the hydrophobic character
Deyu Li et al.
The Journal of organic chemistry, 73(6), 2373-2381 (2008-02-26)
A system consisting of a chiral lithium amide and n-BuLi in tol-d(8) solution was investigated with (1)H and (13)C INEPT DOSY, (6)Li and (15)N NMR, and other 2D NMR techniques. A mixed 2:1 trimeric complex was identified as the major
Jennifer L Rutherford et al.
Journal of the American Chemical Society, 124(2), 264-271 (2002-01-10)
6Li and (13)C NMR spectroscopic studies were carried out on [(6)Li]n-BuLi and [(6)Li]PhLi (RLi) in toluene-d(8) containing the following diamines: N,N,N',N'-tetramethylethylenediamine (TMEDA), N,N,N',N'-tetraethylethylenediamine, 1,2-dipyrrolidinoethane, 1,2-dipiperidinoethane, N,N,N',N'-tetramethylpropanediamine, trans-(R,R)-N,N,N',N'-tetramethylcyclohexanediamine, and (-)-sparteine. Dimers of general structure (RLi)(2)S(2) (S = chelating diamine) are formed
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