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化驗
97%
形狀
liquid
折射率
n20/D 1.426 (lit.)
bp
150-153 °C (lit.)
溶解度
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)
密度
0.963 g/mL at 25 °C (lit.)
SMILES 字串
CCCCCC(Cl)=O
InChI
1S/C6H11ClO/c1-2-3-4-5-6(7)8/h2-5H2,1H3
InChI 密鑰
YWGHUJQYGPDNKT-UHFFFAOYSA-N
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應用
己酰氯用于：
- （±）-7-丁基-6,8-二羟基-3-戊基-3，4-二氢异色烯-1-酮的全合成
- 不对称合成 14-甲基-1-十八烯（桃潜叶蛾的性信息素）
- 制备可在多种有机溶剂中分散的己酰基包覆的纳米纤维
- 全合成天然异卡巴甾醇 ruprechstyril（3-正-戊基-6-甲氧基-8-羟基-1（2H）-异喹啉酮），分离自 Ruprechtia tangarana
- 合成 5-氯-8-羟基-6-甲氧基-3-戊基异香豆素，天然存在的 7-氯-8-羟基-6-甲氧基-3-戊基异香豆素的 5-氯类似物，分离自 Tessmannia densiflora
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
122.0 °F - closed cup
閃點（°C）
50 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Aamer Saeed et al.
Journal of Asian natural products research, 15(10), 1112-1122 (2013-07-23)
A new total synthesis of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one, isolated as R-enantiomer from Geotrichum sp., has been described. Reaction of 4-butyl-3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride in the presence of 1,1,3,3-tetramethyl guanidine and triethyl amine afforded 7-butyl-6,8-dimethoxy-3-pentylisochromen-1-one, which was converted into corresponding 3,4-dihydroisochromen-1-one by
Aamer Saeed
Journal of Asian natural products research, 13(6), 505-511 (2011-05-31)
The synthesis of title isocoumarin, the 5-chloro analog of naturally occurring 7-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, isolated from Tessmannia densiflora is described. Chlorination of ethyl 2-(2-ethoxy-2-oxoethyl)-4,6-dimethoxybenzoate (2) afforded 3-chloro ester (3) followed by hydrolysis to furnish the 2-(carboxymethyl)-3-chloro-4,6-dimethoxybenzoic acid (4) that was converted to
Tao Zhang et al.
Molecules (Basel, Switzerland), 18(5), 5201-5208 (2013-05-09)
An asymmetric synthesis of 14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth has been achieved. The target molecule was synthesized in six linear steps and in 30.3% overall yield from commercially available hexanoyl chloride, (S)-4-benzyloxazolidin-2-one and 1,9-nonanediol. The hexanoyl
Aamer Saeed
Natural product research, 27(13), 1153-1158 (2012-08-14)
A short total synthesis of natural isocarbostyril ruprechstyril (3-n-pentyl-6-methoxy-8-hydroxy-1(2H)-isoquinolinone) isolated from Ruprechtia tangarana is reported. 6,8-Dimethoxy-3-pentylisocoumarin obtained by condensation of 3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride was smoothly converted to O-methylruprechstyril by refluxing with methanamide. Regioselective demethylation of the latter using
One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent.
Pei Huang et al.
ChemSusChem, 5(12), 2319-2322 (2012-11-28)
Got a crush: Native cellulose can be dispersed as nanofibers in organic solvents by ball milling with esterification agents. Milling with hexanoyl chloride/DMF gives hexanoyl-coated nanofibers dispersible in several organic solvents. Milling with succinic anhydride/DMSO results water-dispersible nanofibers. The results
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