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Merck

132551

Sigma-Aldrich

1,2-二氨基环己烷(顺反异构体混合物)

99%

别名:

1,2-环己二胺, 99% 葡萄糖溶液

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About This Item

线性分子式:
C6H10(NH2)2
CAS号:
分子量:
114.19
Beilstein:
506142
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

0.4 mmHg ( 20 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.49 (lit.)

bp

92-93 °C/18 mmHg (lit.)

密度

0.931 g/mL at 25 °C (lit.)

SMILES 字串

NC1CCCCC1N

InChI

1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2

InChI 密鑰

SSJXIUAHEKJCMH-UHFFFAOYSA-N

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一般說明

1,2-二氨基环己烷与同手性化合物以及外消旋形式的 反式 -1,2-二氨基环己烷与对苯二甲醛发生非模板反应,生成 (3 + 3)-环缩合分子三角形 。它作为配体与有机锡形成络合物,作为金属类抗肿瘤药物具有潜在的应用价值

應用

将 1,2-二氨基环己烷用于手性钌 (Ⅳ) 氧配合物的合成

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

158.0 °F - closed cup

閃點(°C)

70 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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(3+ 3)-Cyclocondensation of the enantiopure and racemic forms of trans-1, 2-diaminocyclohexane with terephthaldehyde. Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns.
Chadim M, et al.
Tetrahedron Asymmetry, 12(1), 127-133 (2001)
Chiral ruthenium (IV)-oxo complexes. Structure, reactivities of [Ru (terpy)(Nn N) O]2+Nn N= N, N, N', N'-tetramethyl-1, 2-diaminocyclohexane) and [Ru (Me3 tacn)(cbpy) O]2+ (cbpy=(-)-3, 3'-[(4 S-trans)-1, 3-dioxolane-4, 5-dimethyl]-2, 2'-bipyridine).
Cheng WC, et al.
Inorgorganica Chimica Acta, 242(1), 105-113 (1996)
J J Bonire et al.
Journal of inorganic biochemistry, 83(2-3), 217-221 (2001-03-10)
Platinum compounds containing the ligand 1,2-diaminocyclohexane (DACH) such as tetraplatin [PtCl4(DACH)] have been found to be active in cisplatin-resistant tumour models. In an attempt to develop novel metal-based drugs with a different therapeutic profile to cisplatin, we have synthesised a
Mehmet Aslantaş et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 74(3), 617-624 (2009-08-04)
In this study, the Schiff base ligand trans-N,N'-bis[(2,4-dichlorophenyl) methylidene] cyclohexane-1,2-diamine (L) and its copper(II), nickel(II) and palladium(II) transition metal complexes were prepared and characterized by the analytical and spectroscopic methods. The (1)H((13)C) NMR spectra of the ligand and its diamagnetic
Takuya Kurahashi et al.
Journal of the American Chemical Society, 131(34), 12394-12405 (2009-08-27)
A series of Mn(IV)(salen)(L)(2) complexes bearing different external axial ligands (L = Cl, NO(3), N(3), and OCH(2)CF(3)) from chiral salen ligands with trans-cyclohexane-1,2-diamine as a chiral scaffold are synthesized, to gain insight into conformational properties of metal salen complexes. X-ray

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