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Key Documents

227307

Sigma-Aldrich

Sodium triethylborohydride solution

1.0 M in toluene

Synonym(s):

Sodium triethylborate, Sodium triethylhydridoborate, Sodium triethylhydroborate

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About This Item

Linear Formula:
(C2H5)3NaBH
CAS Number:
Molecular Weight:
121.99
Beilstein:
4151241
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in toluene

density

0.866 g/mL at 25 °C

SMILES string

[Na+].[H][B-](CC)(CC)CC

InChI

1S/C6H16B.Na/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1

InChI key

YDTZLEUIYNMRLQ-UHFFFAOYSA-N

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Application

Reactant for:
  • Preparation of alcohols by hydrogenation of ketones catalyzed by an iron pincer complex
  • Preparation of alkali metal boron monohydride complexes
  • Coordinative substitution reactions
  • Ligand exchange reactions

  • Hydridic reagent

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

44.6 °F - closed cup

Flash Point(C)

7 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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