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642541

Sigma-Aldrich

2-Tributylstannylthiazole

97%

Synonym(s):

(Thiazol-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-thiazole, 2-(Tributylstannyl)thiazole, 2-(Tributyltin)thiazole, Tributyl-2-thiazolylstannane

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About This Item

Empirical Formula (Hill Notation):
C15H29NSSn
CAS Number:
121359-48-6
Molecular Weight:
374.17
MDL number:
MFCD01319057
UNSPSC Code:
12352103
PubChem Substance ID:
24883202
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.5200 (lit.)

bp

307-309 °C (lit.)

density

1.1900 g/mL at 25 °C (lit.)

SMILES string

CCCC[Sn](CCCC)(CCCC)c1nccs1

InChI

1S/3C4H9.C3H2NS.Sn/c3*1-3-4-2;1-2-5-3-4-1;/h3*1,3-4H2,2H3;1-2H;

InChI key

WUOFQGMXQCSPPV-UHFFFAOYSA-N

Application

Reagent for arylation of thiazole by Stille cross-coupling.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

>230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tetrahedron Letters, 47, 599-599 (2006)

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