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Sigma-Aldrich

Gly-His hydrochloride hydrate

≥99.0% (calc. based on dry substance, AT)

Synonym(s):

Glycyl-L-histidine hydrochloride hydrate

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About This Item

Empirical Formula (Hill Notation):
C8H12N4O3 · HCl · xH2O
CAS Number:
3486-76-8
Molecular Weight:
248.67 (anhydrous basis)
Beilstein:
3743779
MDL number:
MFCD00167964
UNSPSC Code:
12352209
PubChem Substance ID:
57651248
NACRES:
NA.22

Assay

≥99.0% (calc. based on dry substance, AT)

optical activity

[α]20/D +31.5±1.0°, c = 2% in H2O (dry matter)

reaction suitability

reaction type: solution phase peptide synthesis

impurities

~1 mol water

application(s)

peptide synthesis

SMILES string

O.Cl.NCC(=O)N[C@@H](Cc1c[nH]cn1)C(O)=O

InChI

1S/C8H12N4O3.ClH.H2O/c9-2-7(13)12-6(8(14)15)1-5-3-10-4-11-5;;/h3-4,6H,1-2,9H2,(H,10,11)(H,12,13)(H,14,15);1H;1H2/t6-;;/m0../s1

InChI key

VGVLXWZHJBRECR-ILKKLZGPSA-N

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Giampiero De Sanctis et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 11(2), 153-167 (2005-12-13)
The pH dependence of redox properties, spectroscopic features and CO binding kinetics for the chelated protohemin-6(7)-L-histidine methyl ester (heme-H) and the chelated protohemin-6(7)-glycyl-L-histidine methyl ester (heme-GH) systems has been investigated between pH 2.0 and 12.0. The two heme systems appear
Michael S Kostelansky et al.
Biochemistry, 43(9), 2475-2483 (2004-03-03)
Structural analysis of recombinant fibrinogen fragment D revealed that the calcium-binding site (beta2-site) composed of residues BbetaAsp261, BbetaAsp398, BbetaGly263, and gammaGlu132 is modulated by the "B:b" interaction. To determine the beta2-site's role in polymerization, we engineered variant fibrinogen gammaE132A in
Flora Carrera et al.
Inorganic chemistry, 43(21), 6674-6683 (2004-10-13)
Knowledge of the complexes formed by N-coordinating ligands and Cu(II) ions is of relevance in understanding the interactions of this ion with biomolecules. Within this framework, we investigated Cu(II) complexation with mono- and polydentate ligands, such as ammonia, ethylenediamine (en)
E Matczak-Jon et al.
Journal of inorganic biochemistry, 12(2), 143-156 (1980-04-01)
1H and 13C nmr studies on the Pd(II)Gly-His complex interaction with cytidine and GMP have shown that the nucleoside binds the palladium complex via N3 nitrogen and the nucleotide binds that complex via N7 nitrogen. The analysis of the Cyd
Girolamo Casella et al.
Inorganic chemistry, 47(11), 4796-4807 (2008-05-08)
We have tested several computational protocols, at the nonrelativistic DFT level of theory, for the calculation of 1J(119Sn, 13C) and 2J(119Sn, 1H) spin-spin coupling constants in di- and trimethyltin(IV) derivatives with various ligands. Quite a good agreement with experimental data
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