Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

686468

Sigma-Aldrich

Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

203998

Sigma-Aldrich

Palladium, powder or granules, 99.99% trace metals basis

348694

Sigma-Aldrich

Palladium, wire, diam. 0.5 mm, 99.9% trace metals basis

203939

Sigma-Aldrich

Palladium, powder, 99.995% trace metals basis

267112

Sigma-Aldrich

Palladium, wire, diam. 1.0 mm, 99.9% trace metals basis

267120

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Palladium, foil, thickness 0.025 mm, 99.9% trace metals basis

267082

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326666

Sigma-Aldrich

Palladium, powder, <1 μm, ≥99.9% trace metals basis

287474

Sigma-Aldrich

Palladium, foil, thickness 0.5 mm, 99.9% trace metals basis

373206

Sigma-Aldrich

Palladium, evaporation slug, diam. × L 0.6 cm × 0.6 cm, 99.95% trace metals basis

464651

Sigma-Aldrich

Palladium, powder, <75 μm, 99.9% trace metals basis

GF57528816

Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%

GF55924241

Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

GF23374661

Palladium, foil, 8mm disks, thickness 0.50mm, as rolled, 99.95%

GF62687795

Palladium, wire reel, 1m, diameter 0.125mm, hard, 99.95%

GF12546581

Palladium, wire reel, 0.1m, diameter 0.25mm, hard, 99.95%

GF40398352

Palladium, wire reel, 1m, diameter 0.25mm, hard, 99.95%

GF02176332

Palladium, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.95%

GF06424398

Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%

GF52273852

Palladium, wire reel, 10m, diameter 0.025mm, as drawn, 99.9%

GF71407650

Palladium, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%

GF61398197

Palladium, wire reel, 0.05m, diameter 1.0mm, hard, 99.95%

GF92472688

Palladium, wire reel, 0.2m, diameter 1.0mm, hard, 99.95%

GF02178761

Palladium, wire reel, 2m, diameter 0.025mm, as drawn, 99.9%

GF05176122

Palladium, wire reel, 5m, diameter 0.05mm, as drawn, 99.9%

GF37597236

Palladium, wire reel, 20m, diameter 0.025mm, as drawn, 99.9%

GF99771261

Palladium, wire reel, 0.5m, diameter 0.25mm, as drawn, 99.99+%

GF99541985

Palladium, tube, 200mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%