Hydrothermal synthesis of tetragonal BaTiO3 nanotube arrays with high dielectric performance.

Hydrothermal synthesis of tetragonal BaTiO3 nanotube arrays with high dielectric performance.

Journal of nanoscience and nanotechnology (2014-04-18)

Liming Wang, Xiangyun Deng, Jianbao Li, Xinxing Liao, Guoqing Zhang, Chunpeng Wang, Kuifan Su

ABSTRACT

Tetragonal Barium titanate (BaTiO3) nanotube arrays have been prepared using the template-assisted hydrothermal method combined with an annealing process. The in-situ chemical conversion of TiO2 nanotube array templates ensured that BaTiO3 maintained the morphology of the nanotube architectures. Moreover, X-ray diffraction and Raman spectrum characterization were used to confirm that the BaTiO3 nanotube arrays had a tetragonal phase after the use of a simple annealing technique. Typical hysteresis loops showed their ferroelectricity, with the remanent polarization and coercive fields being 2.57 microC/cm2 and 2.52 kV/cm, respectively. The relative dielectric constant of the tetragonal BaTiO3 nanotube arrays reached up to 1000 and the dielectric loss was as low as 0.02 at 1 kHz at room temperature.

MATERIALS

Product Number

Brand

Product Description

208108

Sigma-Aldrich

Barium titanate(IV), powder, <3 μm, 99%

338842

Sigma-Aldrich

Barium titanate(IV), powder, <2 μm, 99.5% trace metals basis

467634

Sigma-Aldrich

Barium titanate(IV), nanopowder (cubic crystalline phase), <100 nm particle size (BET), ≥99% trace metals basis

GF52005596

Titanium, tube, 500mm, outside diameter 9.5mm, inside diameter 8.2mm, wall thickness 0.65mm, annealed, 99.6+%

GF51463357

Titanium, tube, 200mm, outside diameter 10.3mm, inside diameter 8.7mm, wall thickness 0.8mm, annealed, 99.6+%

GF58567067

Titanium, rod, 100mm, diameter 5mm, annealed, 99.6+%

GF54883581

Titanium, rod, 1000mm, diameter 3.0mm, annealed, 99.6+%

GF56868766

Titanium, wire reel, 25m, diameter 1.0mm, annealed, 99.6+%

GF41437830

Titanium, tube, 100mm, outside diameter 1.05mm, inside diameter 0.75mm, wall thickness 0.15mm, annealed, 99.6+%

GF91859967

Titanium, rod, 100mm, diameter 9.5mm, annealed, 99.99+%

GF98611623

Titanium, rod, 200mm, diameter 8.0mm, as drawn, 99.99+%

GF71783354

Titanium, wire reel, 100m, diameter 0.75mm, as drawn, 99.6+%

GF13900205

Titanium, tube, 100mm, outside diameter 0.51mm, inside diameter 0.35mm, wall thickness 0.08mm, annealed, 99.6+%

GF26602321

Titanium, tube, 500mm, outside diameter 25.4mm, inside diameter 23.62mm, wall thickness 0.89mm, annealed, 99.6+%

GF72193114

Titanium, tube, 500mm, outside diameter 2.03mm, inside diameter 1.63mm, wall thickness 0.2mm, annealed, 99.6+%

GF69259315

Titanium, rod, 500mm, diameter 6mm, annealed, 99.6+%

GF17705516

Titanium, rod, 200mm, diameter 3.0mm, annealed, 99.6+%

GF46132534

Titanium, wire reel, 100m, diameter 0.25mm, as drawn, 99.6+%

GF35061083

Titanium, tube, 200mm, outside diameter 6.35mm, inside diameter 5.53mm, wall thickness 0.41mm, annealed, 99.6+%

GF65336700

Titanium, rod, 200mm, diameter 2mm, annealed, 99.6+%

GF05438066

Titanium, tube, 1000mm, outside diameter 1.6mm, inside diameter 1.2mm, wall thickness 0.2mm, hard, 99.6+%

GF14377631

Titanium, wire reel, 25m, diameter 0.25mm, annealed, 99.6+%

GF43403431

Titanium, wire reel, 500m, diameter 0.20mm, annealed, 99.6+%

GF55775975

Titanium, wire reel, 25m, diameter 0.25mm, as drawn, 99.6+%

GF95731960

Titanium, tube, 500mm, outside diameter 3.0mm, inside diameter 1.5mm, wall thickness 0.75mm, annealed, 99.6+%

GF61322699

Titanium, rod, 100mm, diameter 2mm, annealed, 99.6+%

GF94150593

Titanium, wire reel, 10m, diameter 1.5mm, as drawn, 99.6+%

GF96391402

Titanium, wire reel, 25m, diameter 0.20mm, annealed, 99.6+%

GF76266423

Titanium, wire reel, 0.5m, diameter 1.0mm, annealed, 99.6+%

266035

Sigma-Aldrich

Titanium, wire, diam. 1.0 mm, 99.99% trace metals basis