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369713

Sigma-Aldrich

1-Benzyl-2-methylimidazole

technical grade, 90%

Synonym(s):

1-Benzyl-2-methyl-1H-imidazole, 1-Phenylmethyl-2-methylimidazole, 2-Methyl-1-(phenylmethyl)-1H-imidazole, 2-Methyl-N-benzylimidazole, N-Benzyl-2-methylimidazole

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About This Item

Empirical Formula (Hill Notation):
C11H12N2
CAS Number:
13750-62-4
Molecular Weight:
172.23
EC Number:
237-333-8
MDL number:
MFCD00010637
UNSPSC Code:
12352100
PubChem Substance ID:
24863013
NACRES:
NA.22

grade

technical grade

Assay

90%

refractive index

n20/D 1.5645 (lit.)

bp

125-127 °C/3 mmHg (lit.)

density

1.105 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Cc1nccn1Cc2ccccc2

InChI

1S/C11H12N2/c1-10-12-7-8-13(10)9-11-5-3-2-4-6-11/h2-8H,9H2,1H3

InChI key

FBHPRUXJQNWTEW-UHFFFAOYSA-N

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General description

1-Benzyl-2-methylimidazole is a nitrogen heterocycle and forms mixed ligand Pt(II) complexes. 1-Benzyl-2-methylimidazole on treatement with ammonia and sodium yields 2-methylimidazole. Deposition of plasma-polymerized 1-benzyl-2-methylimidazole (PPBMI) thin films onto glass substrates by glow discharge technique have been reported.

Application

1-Benzyl-2-methylimidazole may be employed as catalyst to investigate the effect of catalysts on the curing reaction of the biphenyl epoxy (4,4′-diglycidyloxy-3,3′,5,5′-tetramethyl biphenyl)dicyclopentadiene type phenolic resin system.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Kinetic study of the effect of catalysts on the curing of biphenyl epoxy resin.
Han S, et al.
Journal of Applied Polymer Science, 68(7), 1125-1137 (1998)
Studies on imidazole compounds; a synthesis of imidazoles with functional groups in the 2-position.
R G JONES
Journal of the American Chemical Society, 71(2), 383-386 (1949-02-01)
Structural and Optical Properties of Plasma-Polymerized 1-BENZYL-2-METHYLIMIDAZOLE Thin Films.
Sarker RB and Bhuiyan AH.
International Journal of Modern Physics B, 25(14), 1941-1955 (2011)
Julien Sarju et al.
Dalton transactions (Cambridge, England : 2003), (39)(39), 5302-5312 (2008-10-02)
The nitrile ligands in trans-[PtX2(PhCN)2] (X = Cl, Br, I) undergo sequential 1,3 dipolar cycloadditions with nitrones R1R2C=N+(Me)-O(-) (R1 = H, R2 = Ph; R1 = CO2Et, R2 = CH2CO2Et) to selectively form the Delta4-1,2,4-oxadiazoline complexes trans-[PtX2(PhCN) (N=C(Ph)-O-N(Me)-CR1R2)] or trans-[PtX2(N=C(Ph)-O-N(Me)-CR1R2)2]
Rahul A Patil et al.
Analytical and bioanalytical chemistry, 410(19), 4645-4655 (2018-01-31)
The rapid expansion in the study and use of ionic liquids (ILs) is a result of their unique properties including negligible volatility, high thermal stability, and ability to dissolve disparate compounds. However, because ILs have infinitely variable structures (often referred

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