sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

GF50019937

Nickel, foil, 6mm disks, thickness 0.009mm, 99.95%

GF78965263

Nickel, foil, 6mm disks, thickness 0.05mm, as rolled, 99.99+%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF64818850

Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%

GF88937162

Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%

GF89699315

Nickel, tube, 500mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, hard, 99.5%

GF81790690

Nickel, foil, 10mm disks, thickness 0.015mm, 99.9%

GF64774345

Nickel, foil, 10m coil, thickness 0.125mm, coil width 50mm, annealed, 99%

GF12092778

Nickel, pellets, 20g, max. size 20mm, 99.99+%

GF85861042

Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99%

GF77692786

Nickel, rod, 1000mm, diameter 20.0mm, 99%

GF57292005

Nickel, foil, 0.5m coil, thickness 0.005mm, as rolled, 99.9%

GF35840291

Nickel, wire reel, 1m, diameter 0.4mm, as drawn, 99.99+%

GF46693109

Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.95%

GF52578872

Nickel, foil, 25x25mm, thickness 0.25mm, as rolled, 99.999%

GF83416798

Nickel, wire reel, 10m, diameter 0.01mm, as drawn, 99.98%

GF40497970

Nickel, foil, 5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF28868439

Nickel, foil, 50mm disks, thickness 0.005mm, as rolled, 99.9%

GF08224321

Nickel, foil, 5m coil, thickness 0.025mm, annealed, 99%

GF39029306

Nickel, foil, 50mm disks, thickness 0.025mm, annealed, 99%

GF82923374

Nickel, foil, 4mm disks, thickness 0.3mm, as rolled, 100%

GF82156912

Nickel, rod, 100mm, diameter 12.0mm, 99%

GF87261228

Nickel, foil, 10mm disks, thickness 0.003mm, 99.95%

GF13212807

Nickel, pellets, 50g, max. size 5mm, 99.99+%