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Iodosulfuron-methyl-sodium

PESTANAL®, analytical standard

Synonym(s):

Methyl 4-iodo-2-[3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulfonyl]benzoate sodium salt

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About This Item

Empirical Formula (Hill Notation):
C14H13IN5NaO6S
CAS Number:
Molecular Weight:
529.24
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COC(=O)c1ccc(I)cc1S(=O)(=O)N([Na])C(=O)Nc2nc(C)nc(OC)n2

InChI

1S/C14H14IN5O6S.Na/c1-7-16-12(19-14(17-7)26-3)18-13(22)20-27(23,24)10-6-8(15)4-5-9(10)11(21)25-2;/h4-6H,1-3H3,(H2,16,17,18,19,20,22);/q;+1/p-1

InChI key

JUJFQMPKBJPSFZ-UHFFFAOYSA-M

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General description

Iodosulfuron-methyl-sodium is a systemic sulfonylurea herbicide that affects the activity of acetolactate synthase (ALS) enzyme causing plant deformation, growth retardation, chlorosis and eventually death. It is absorbed by above-ground parts of weeds. This herbicide can also penetrate surface and groundwater as it has high mobility in environment.

Application

Iodosulfuron-methyl-sodium may have been used as stock reference standard in Liquid chromatography tandem-mass spectrometry (LC-MS) analysis done for the determination of sulfonylurea herbicides in tap and leaching water.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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José G Vázquez-García et al.
Frontiers in plant science, 11, 553948-553948 (2020-11-17)
Different Lolium species, common weeds in cereal fields and fruit orchards in Chile, were reported showing isolated resistance to the acetyl CoA carboxylase (ACCase), acetolactate synthase (ALS) and 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibiting herbicides in the late 1990s. The first case
Microbial and enzymatic activity of soil contaminated with a mixture of diflufenican + mesosulfuron-methyl + iodosulfuron-methyl-sodium.
Bacmaga M
Environmental Science and Pollution Research International, 22(1), 643-656 (2015)
María Paz Castro Tapia et al.
Frontiers in plant science, 11, 951-951 (2020-07-17)
Seed treatments with antagonistic bacteria could reduce the severity of crown and root rot diseases in wheat crops. The objective of this study was to evaluate the potential antagonistic activity of a bacterial consortium of three Chilean strains of Pseudomonas
Trace analysis of sulfonylurea herbicides in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry.
Fenoll J
Talanta, 101, 273-282 (2012)
Ana Zabalza et al.
Plants (Basel, Switzerland), 9(9) (2020-09-20)
Quinate (1,3,4,5-tetrahydroxycyclohexanecarboxylate) is a compound synthesized in plants through a side-branch of the shikimate biosynthesis pathway, which is accumulated after glyphosate and acetolactate synthase inhibiting herbicides (ALS-inhibitors) and has phytotoxic potential. The objective of this study was to evaluate the

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