sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

GF25500079

Nickel, foil, 2m coil, thickness 0.5mm, annealed, 99.98%

GF92543564

Nickel, foil, 150x300mm, thickness 0.25mm, annealed, 99.98%

GF37939506

Nickel, mesh, 30x30mm, nominal aperture 0.34mm, thickness 0.025mm, wire diameter 0.041mm, 70 wires/inch, open area 80%, electro-formed mesh, 99.9%

GF32919824

Nickel, foil, 50x50mm, thickness 0.25mm, as rolled, 99.99+%

GF15707729

Nickel, foil, not light tested, 300x300mm, thickness 0.0125mm, annealed, 99%

GF09874424

Nickel, wire reel, 10m, diameter 0.25mm, hard, 99.98%

GF02127068

Nickel, foil, 10mm disks, thickness 0.0075mm, 99.9%

GF56028720

Nickel, foil, 0.5m coil, thickness 0.038mm, 99.9%

GF60017510

Nickel, foil, 0.2m coil, thickness 0.004mm, hard, 99%

GF69797659

Nickel, foil, 25x25mm, thickness 0.25mm, annealed, 99%

GF54340219

Nickel, foil, 0.5m coil, thickness 0.025mm, coil width 600mm, as rolled, 99%

GF22004334

Nickel, foil, 150x300mm, thickness 0.5mm, annealed, 99.98%

GF05585711

Nickel, foil, light tested, 50x50mm, thickness 0.05mm, as rolled, 100%

GF69666328

Nickel, rod, 1000mm, diameter 6.35mm, 99%

GF18549614

Nickel, foil, 2m coil, thickness 0.075mm, annealed, 99%

GF28374767

Nickel, foil, not light tested, 50x50mm, thickness 0.007mm, 99.95%

GF54176812

Nickel, wire reel, 10m, diameter 0.4mm, as drawn, 99%

GF39005669

Nickel, foil, 2m coil, thickness 0.025mm, annealed, 99%

GF71979283

Nickel, foil, 50x50mm, thickness 1.0mm, as rolled, 99.99+%

GF35840291

Nickel, wire reel, 1m, diameter 0.4mm, as drawn, 99.99+%

GF83416798

Nickel, wire reel, 10m, diameter 0.01mm, as drawn, 99.98%

GF89678570

Nickel, wire reel, 100m, diameter 0.025mm, as drawn, 99.98%

GF91622853

Nickel, foil, 4mm disks, thickness 0.003mm, 99.95%

GF35355315

Nickel, wire reel, 0.1m, diameter 0.75mm, as drawn, 99.99+%