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Systematic approach in Mg

Analytica chimica acta (2017-09-17)
L Lvova, C Guanais Gonçalves, L Prodi, M Sgarzi, N Zaccheroni, M Lombardo, A Legin, C Di Natale, R Paolesse
RÉSUMÉ

A systematic study of a series of diaza-18-crown-6 8-hydroxyquinoline (DCHQ) chemosensors, devoted to Mg(II) ion detection, was performed. Functionalization of DCHQ by peripheral substituents allowed the development of novel all-solid-state optodes via inclusion inside PVC-based polymeric films. The influence on the DCHQ-based optode response of the lipophilic sites functionalization and of the nature of the plasticizer, was investigated. Fluorimetric studies on optodes sensitivity towards a number of different metal cations (Ca

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