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658383

Sigma-Aldrich

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Synonym(s):

[(ppy)2IrCl]2

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About This Item

Empirical Formula (Hill Notation):
C44H32Cl2Ir2N4
CAS Number:
92220-65-0
Molecular Weight:
1072.09
MDL number:
MFCD07784515
UNSPSC Code:
12352103
PubChem Substance ID:
24884350
NACRES:
NA.23

form

solid

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

465 nm

SMILES string

Cl[Ir](c1ccccc1-c2ccccn2)c3ccccc3-c4ccccn4.Cl[Ir](c5ccccc5-c6ccccn6)c7ccccc7-c8ccccn8

InChI

1S/4C11H9N.2ClH.2Ir/c4*1-2-6-10(7-3-1)11-8-4-5-9-12-11;;;;/h4*1-9H;2*1H;;/q;;;;;;2*+1/p-2

InChI key

NARZJSRZFGZBIZ-UHFFFAOYSA-L

Application

Precursor for several OLED Iridium compounds. Has some use as a catalyst and in OLEDs.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Journal of the American Chemical Society, 106, 6647-6647 (1984)

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