Direkt zum Inhalt
Merck

Au-containing all-carbon 1,3-dipoles: generation and [3+2] cycloaddition reactions.

Journal of the American Chemical Society (2008-08-30)
Guozhu Zhang, Liming Zhang
ZUSAMMENFASSUNG

A novel approach to generate Au-containing all-carbon 1,3-dipoles is developed via an unprecedented migration-fragmentation of ketals/acetals. These in situ generated dipoles undergo rapid [3+2] cycloaddition under mild conditions with various enones/enals, electron-rich aromatic aldehydes, and N-benzylindole, leading to flexible formation of highly functionalized dihydrofurans and cyclopentenes.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
p-Anisaldehyd, 98%
SKU
Packungsgröße
Verfügbarkeit
Preis
Menge
Sigma-Aldrich
p-Anisaldehyd, ≥97.5%, FCC, FG
SKU
Packungsgröße
Verfügbarkeit
Preis
Menge
Supelco
p-Anisaldehyd, analytical standard
SKU
Packungsgröße
Verfügbarkeit
Preis
Menge