407437

1,6-Heptadiin

97%

• Lineare Formel: HC≡C(CH₂)₃C≡CH
• CAS-Nummer: 2396-63-6
• Molekulargewicht: 92.14
• EG-Nummer: 219-253-5
• MDL-Nummer: MFCD00014925
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24865453
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.441 (lit.)
• bp: 111.5 °C (lit.)
• Dichte: 0.805 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: C#CCCCC#C
• InChI: 1S/C7H8/c1-3-5-7-6-4-2/h1-2H,5-7H2
• InChIKey: RSPZSDWVQWRAEF-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. Cyclocopolymerization of 1,6-heptadiyne with dipropargyl ether under nitrogen atmosphere using KSCN, KBr and KI as initiators in N,N-dimethyl formamide has been studied.

Anwendung

1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne).

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Danger
• H-Sätze: H225
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P243
• Gefahreneinstufungen: Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 2
• Flammpunkt (°F): 48.2 °F - closed cup
• Flammpunkt (°C): 9 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter