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  • Convergent total syntheses of fluvibactin and vibriobactin using molybdenum(VI) oxide-catalyzed dehydrative cyclization as a key step.

Convergent total syntheses of fluvibactin and vibriobactin using molybdenum(VI) oxide-catalyzed dehydrative cyclization as a key step.

Chemical communications (Cambridge, England) (2008-07-26)
Akira Sakakura, Shuhei Umemura, Kazuaki Ishihara
ABSTRACT

Efficient total syntheses of fluvibactin and vibriobactin have been achieved via molybdenum(VI) oxide-catalyzed dehydrative cyclization, Sb(OEt)(3)-catalyzed ester-amide transformation, and WSCI and HOAt-promoted dehydrative amide formation.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Sodium molybdate, anhydrous, powder, −100 mesh particle size, 99.9% trace metals basis
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Sodium molybdate dihydrate, ≥99.5%, suitable for plant cell culture
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Sodium molybdate dihydrate, ACS reagent, ≥99%
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