- Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2(S2C2)CN)2)2] in the model reductive half reaction of sulfite oxidase.
Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2(S2C2)CN)2)2] in the model reductive half reaction of sulfite oxidase.
Chemical communications (Cambridge, England) (2002-09-25)
K Nagarajan, P K Chaudhury, B R Srinivasan, S Sarkar
PMID12269282
ABSTRACT
pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.
MATERIALS