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Sigma-Aldrich

2-Methyl-1-(trimethylsilyloxy)-1-propene

99%

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About This Item

Linear Formula:
(CH3)2C=CHOSi(CH3)3
CAS Number:
6651-34-9
Molecular Weight:
144.29
MDL number:
MFCD00192331
UNSPSC Code:
12352100
PubChem Substance ID:
24865629

Assay

99%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

114-116 °C/650 mmHg (lit.)

density

0.785 g/mL at 25 °C (lit.)

SMILES string

C\C(C)=C\O[Si](C)(C)C

InChI

1S/C7H16OSi/c1-7(2)6-8-9(3,4)5/h6H,1-5H3

InChI key

KZVPFSJPLBOVLO-UHFFFAOYSA-N

General description

2-Methyl-1-(trimethylsilyloxy)-1-propene is an enol ether.

Application

2-Methyl-1-(trimethylsilyloxy)-1-propene may be used as reagent in the direct conversion of α-amino acids into β-amino aldehydes.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

57.2 °F - closed cup

Flash Point(C)

14 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Carlos J Saavedra et al.
Organic & biomolecular chemistry, 10(22), 4448-4461 (2012-05-05)
A direct method for the transformation of α-amino acids into β-amino aldehydes was developed, and applied to the modification of the C-terminal residue of peptides. The method takes place in good yields and under mild conditions. The application of this
L Nassi et al.
Mutation research, 198(1), 53-60 (1988-03-01)
Generation of triplet ketones, either chemically through thermal decomposition of 3-hydroxymethyl-3,4,4-trimethyl-1,2-dioxetane and 3-[N-(pyridino)carbamoyl]methyl-3,4,4-trimethyl-1,2-dioxetane++ + or enzymatically via the aerobic oxidation of isobutyraldehyde trimethylsilyl enol ether catalyzed by horse-radish peroxidase, triggers the SOS function sfiA in E. coli. Although the observed
G Cilento et al.
Toxicology letters, 67(1-3), 17-28 (1993-04-01)
Selected enzymatic systems can efficiently produce a product in the electronically excited triplet state. Earlier, only the formation of electronically excited singlet species was known. The formation of triplet species has been demonstrated with both normal substrates/metabolites and with xenobiotics

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