- Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.
Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.
Chemical communications (Cambridge, England) (2012-04-21)
Kenji Hirai, Shuhei Furukawa, Mio Kondo, Mikhail Meilikhov, Yoko Sakata, Osami Sakata, Susumu Kitagawa
PMID22516961
ABSTRACT
Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.