335002

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

• Synonym(s): Dihydridocarbonyltris(triphenylphosphine)ruthenium
• Linear Formula: [(C₆H₅)₃P]₃Ru(CO)H₂
• CAS Number: 25360-32-1
• Molecular Weight: 919.79
• UNSPSC Code: 12352202
• PubChem Substance ID: 24860277
• NACRES: NA.22

Properties

• reaction suitability: core: ruthenium; reagent type: catalyst; reaction type: C-H Activation
• mp: 161-163 °C (lit.)
• SMILES string: [RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
• InChI: 1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
• InChI key: MLIYPCQSOXNTLJ-UHFFFAOYSA-N

Description

Application

• Catalyst for conversion of 1,4-alkynediols into pyrroles
• Catalyst for oxidation of primary alcohols to methyl esters
• Catalyst for rearrangement of oximes to amides
• Catalyst for C-C coupling via directed C-H activation
• Catalyst for enyne cyclization

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302 + H312 + H332
• Precautionary Statements: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves