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Sigma-Aldrich

Phenylsilane

97%

Synonym(s):

Monophenylsilane

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About This Item

Linear Formula:
C6H5SiH3
CAS Number:
694-53-1
Molecular Weight:
108.21
Beilstein:
2935169
EC Number:
211-772-5
MDL number:
MFCD00013478
UNSPSC Code:
12352103
PubChem Substance ID:
24860291
NACRES:
NA.22

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.510 (lit.)

bp

120 °C (lit.)

density

0.877 g/mL at 25 °C (lit.)

SMILES string

[SiH3]c1ccccc1

InChI

1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3

InChI key

PARWUHTVGZSQPD-UHFFFAOYSA-N

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Application

Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

46.4 °F - closed cup

Flash Point(C)

8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The Role of Precursor?Decomposition Kinetics in Silicon?Nanowire Synthesis in Organic Solvents.
Lee DC
Angewandte Chemie (International Edition in English), 44(23), 3573-3577 (2005)
Chayanon Ngambenjawong et al.
Bioconjugate chemistry, 27(12), 2854-2862 (2016-10-26)
Peptide cyclization is a strategy used to improve stability and activity of peptides. The most commonly used cyclization method is disulfide bridge formation of cysteine-containing peptides, as is typically found in nature. Over the years, an increasing number of alternative
Synthesis of poly (arylene phosphine oxide) by nickel-catalysed coupling polymerization.
Ghassemi H
Polymer, 38(12), 3139-3143 (1997)
Xiaoyan Yin et al.
Colloids and surfaces. B, Biointerfaces, 195, 111271-111271 (2020-08-01)
Lipidated peptide amphiphiles exhibit high affinity for plasma cell membranes, good cell internalization and improved stability against degradation, which make them attractive as a drug delivery system. However, low drug loading capacity limits their application for drug delivery. Herein, we
Photopolymerization of Methyl methacrylate with Phenylsilane.
Hong L-Y
Bull. Korean Chem. Soc., 16(4), 360-363 (1995)
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