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159042

Sigma-Aldrich

Luperox® P, tert-Butyl peroxybenzoate

98%

Synonym(s):

tert-Butyl peroxybenzoate, tert-Butyl perbenzoate

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About This Item

Linear Formula:
C6H5COOOC(CH3)3
CAS Number:
614-45-9
Molecular Weight:
194.23
Beilstein:
1342734
EC Number:
210-382-2
MDL number:
MFCD00008802
UNSPSC Code:
12352100
PubChem Substance ID:
24849787
NACRES:
NA.22

vapor density

6.7 (vs air)

vapor pressure

3.36 mmHg ( 50 °C)

Assay

98%

form

liquid

refractive index

n20/D 1.499 (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

solubility

water: soluble 1.18 g/L

density

1.021 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)OOC(=O)c1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3

InChI key

GJBRNHKUVLOCEB-UHFFFAOYSA-N

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General description

tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane has been reported.

Application

Luperox was employed as polymerization and cross-linking catalyst. It was also was employed as initiator during:
  • grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene)
  • preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Signal Word

Danger

Hazard Statements

H242,H315,H317,H332,H410

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 2

Flash Point(F)

200.1 °F - closed cup

Flash Point(C)

93.4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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ACS applied materials & interfaces, 3(7), 2410-2416 (2011-06-08)
Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates.
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Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
Jia-Jia Cao et al.
Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
Chengguo Liu et al.
Polymers, 11(5) (2019-05-10)
New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
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Humans are exposed to various peroxy and hydroperoxy compounds which are in use in the cosmetic, pharmaceutical and polymer industries and which are also generated as a result of the peroxidative metabolic conversion of certain lipids. This study was designed
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