Skip to Content
Merck
All Photos(1)

Key Documents

794279

Sigma-Aldrich

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

Synonym(s):

Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C43H37ClNiP2
CAS Number:
Molecular Weight:
709.85
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

solid

Quality Level

reaction suitability

core: nickel
reagent type: catalyst

mp

195-200 °C

storage temp.

2-8°C

SMILES string

Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1

InChI key

QVGJKVLYWZGANE-UHFFFAOYSA-M

Application

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 1B - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service