- Mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin in CH3OH.
Mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin in CH3OH.
Organic letters (2006-06-30)
Xiao-Qing Zhu, Jian-Yu Zhang, Lian-Rui Mei, Jin-Pei Cheng
PMID16805553
ABSTRACT
[reaction: see text] The mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin (TPPFe(II)) in CH(3)OH is discovered for the first time by using a laser flash technique. The results show that the NO transfer is completed by NO(+) transfer followed by electron transfer rather than direct NO transfer in one step.
MATERIALS