- Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate.
Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate.
Chemical communications (Cambridge, England) (2010-10-23)
Yoichiro Kuninobu, Mitsumi Nishi, Kazuhiko Takai
PMID20967333
ABSTRACT
Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl(3), in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.
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