- Ruthenium-catalyzed direct arylations through C-H bond cleavages.
Ruthenium-catalyzed direct arylations through C-H bond cleavages.
Topics in current chemistry (2010-01-01)
Lutz Ackermann, Rubén Vicente
PMID21500408
ABSTRACT
Stoichiometric cycloruthenation reactions of substrates containing Lewis-basic functionalities set the stage for efficient ruthenium-catalyzed C-H bond functionalization reactions. Thereby, selective addition reactions of C-H bonds across alkenes or alkynes enabled atom-economical synthesis of substituted arenes. More recently, ruthenium-catalyzed direct arylation reactions were examined, which display an unparalleled scope and, hence, represent economically and environmentally benign alternatives to traditional cross-coupling chemistry.
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Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.1μm, specific density 122μg/cm2, permanent mylar 3.5μm support, 99.9%
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Ruthenium, Ruthenium, foil, 6x6mm, thickness 1.0mm, 99.9%
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Ruthenium, Ruthenium, bar, 25mm x 2mm x 2mm, 99.9%
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Ruthenium, Ruthenium, pellets, 5g, max. size 10mm, 99.9%
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Ruthenium, Ruthenium, rod, 12.7mm, diameter 12.7mm, 99.9%
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Ruthenium, Ruthenium, bar, 50mm x 2mm x 2mm, 99.9%
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Ruthenium, Ruthenium, foil, 10x10mm, thickness 1.0mm, 99.9%
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Ruthenium, Ruthenium, foil, 25x25mm, thickness 1.0mm, 99.9%
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Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.025μm, specific density 30.5μg/cm2, permanent mylar 3.5μm support, 99.9%
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