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36121

Supelco

Butocarboxim

PESTANAL®, analytical standard, mixture of isomers

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O2S
CAS Number:
Molecular Weight:
190.26
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CNC(=O)O\N=C(/C)C(C)SC

InChI

1S/C7H14N2O2S/c1-5(6(2)12-4)9-11-7(10)8-3/h6H,1-4H3,(H,8,10)/b9-5+

InChI key

SFNPDDSJBGRXLW-WEVVVXLNSA-N

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General description

Butocarboxim is a carbamate pesticide commonly used as an insecticide and miticide. The mode of action of butocarboxim involves the inhibition of the enzyme activity of acetylcholinesterase (AChE).

Application

Butocarboxim may be used as an analytical reference standard for the determination of the analyte in agricultural products, crude extracts of fruits and vegetables, and bovine milk by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

73.4 - 194.0 °F

Flash Point(C)

23 - 90 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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An enzyme-linked chemiluminescent immunoassay developed for detection of Butocarboxim from agricultural products based on monoclonal antibody.
Fang Q, et al.
Food Chemistry, 166, 372-379 (2015)
Multi-residue method for rapid screening and confirmation of pesticides in crude extracts of fruits and vegetables using isocratic liquid chromatography with electrospray tandem mass spectrometry.
Taylor MJ, et al.
Journal of Chromatography A, 982(2), 225-236 (2002)
F Garcia-Marí et al.
Journal of economic entomology, 94(6), 1558-1563 (2002-01-05)
Glass vials coated internally with an insecticide were used as a resistance monitoring technique for testing field populations of the woolly whitefly, Aleurothrixus floccosus (Maskell), collected from citrus. The distribution of resistance to the insecticide butocarboxim in citrus orchards from
Simple and rapid assay for analyzing residues of carbamate insecticides in bovine milk: hot water extraction followed by liquid chromatography-mass spectrometry.
Bogialli S, et al.
Journal of Chromatography A, 1054(1-2), 351-357 (2004)
N Aharonson et al.
Zeitschrift fur Lebensmittel-Untersuchung und -Forschung, 180(2), 96-100 (1985-02-01)
A gas-chromatographic method is described for determination of residues of butocarboxime (Drawin), its structural isomer aldicarb (Temik), and their toxic sulfoxide and sulfone metabolites. These compounds were determined intact, by gas chromatography employing a thermionic specific detector (TSD). Breakdown of

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