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  • Preparation and study of an f,f,f',f'' covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad.

Preparation and study of an f,f,f',f'' covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad.

Chemical communications (Cambridge, England) (2012-12-14)
Thomas Just Sørensen, Manuel Tropiano, Octavia A Blackburn, James A Tilney, Alan M Kenwright, Stephen Faulkner
ABSTRACT

A heterotrimetallic tetranuclear lanthanide complex containing two dysprosium ions, a terbium ion and a europium ion has been prepared by coupling three kinetically stable complexes together using the Ugi reaction. The covalently linked trimetallic system exhibits luminescence from all the different lanthanide centres.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Dysprosium, chips, 99.9% trace rare earth metals basis
Sigma-Aldrich
Dysprosium, ingot, 99.9% trace rare earth metals basis