656577

1,3-Diisopropylimidazolium chloride

97%

• Synonym(s): N,N′-(Isopropyl)imidazolium chloride
• Empirical Formula (Hill Notation): C₉H₁₇ClN₂
• CAS Number: 139143-09-2
• Molecular Weight: 188.70
• MDL number: MFCD03840577
• UNSPSC Code: 12352005
• PubChem Substance ID: 24884209
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• reaction suitability: reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 182-186 °C
• greener alternative category: Aligned,
• SMILES string: [Cl-].CC(C)n1cc[n+](c1)C(C)C
• InChI: 1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
• InChI key: DOFXKPAOJLLPII-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

1,3-Diisopropylimidazolium chloride may be used to prepare:

• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
• (C₉H₇)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves