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Boron trifluoride - 1-butanol solution

~10% in 1-butanol (∼1.3 M), for GC derivatization, LiChropur™

Synonym(s):

BF3 - Butanol solution

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About This Item

CAS Number:
7637-07-2
MDL number:
MFCD00011316
UNSPSC Code:
12000000
PubChem Substance ID:
329769284
NACRES:
NA.05

grade

for GC derivatization

Quality Level

100

form

solution

quality

LiChropur™
for esterification of fatty acids for GC purposes

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

concentration

~10% in 1-butanol (∼1.3 M)

technique(s)

gas chromatography (GC): suitable

density

0.87 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI key

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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Application

Learn more in the Product Information
Boron trifluoride-1-butanol solution may be used as a derivatization agent in the separation and identification of water‐soluble low‐molecular‐weight carboxylic acids using capillary electrophoresis (CE) and gas chromatography coupled with mass spectrometry (GC-MS).
Reagent for the esterification of carboxylic acids for GC analysis

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

95.0 °F - closed cup

Flash Point(C)

35 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK6374
BCCG3924
BCCD9963
BCCB8315
BCBV9593

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Capillary electrophoresis determinative and GC-MS confirmatory method for water-soluble organic acids in airborne particulate matter and vehicle emission.
Dabek-Zlotorzynska E, et al.
Journal of Separation Science, 28(13), 1520-1528 (2005)
Casey R Wade et al.
Chemical communications (Cambridge, England), 46(34), 6380-6381 (2010-08-07)
The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph(2)MeP)C(6)H(4)(BF(3)) stabilizes these compounds against hydrolysis.
Joanna E Rode et al.
Chirality, 24(1), 5-16 (2011-12-06)
Stabilization energies of the electron donor-acceptor sulfinimine···BF(3) complexes calculated at either the B3LYP/aug-cc-pVTZ or the MP2/aug-cc-pVTZ level do not allow to judge, whether the N- or O-atom in sulfinimine is stronger electron-donor to BF(3) . The problem seems to be
G K Surya Prakash et al.
Organic letters, 13(15), 4128-4131 (2011-07-14)
The one-pot synthesis of 1,1,1-trifluoro- and 1,1-difluoro-2,2-diarylethanes from arenes and fluorinated hemiacetals in the BF(3)-H(2)O system is described. The reaction is simple, clean, and convenient, eliminating the use of organic solvents and other expensive acid systems. BF(3)-H(2)O is economic, is
Brieuc Guillerm et al.
Macromolecular rapid communications, 33(19), 1600-1612 (2012-07-05)
Polyoxazolines (POx) are increasingly being studied as polymeric building blocks due to the possibility of affording tunable properties. Additionally, as the biocompatibility and stealth behavior of POx are similar to that of poly(ethylene glycol) (PEG), it has become challenging to
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