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  • Palladium-catalyzed formylation of aryl halides with tert-butyl isocyanide.

Palladium-catalyzed formylation of aryl halides with tert-butyl isocyanide.

Organic letters (2014-06-24)
Xiao Jiang, Jin-Mei Wang, Ying Zhang, Zhong Chen, Yong-Ming Zhu, Shun-Jun Ji
초록

A novel palladium-catalyzed formylation of aryl halides with isocyanide in the presence of Et3SiH has been demonstrated, which provides a strategy toward important aldehydes with moderate to excellent yield. The advantage of this reaction includes milder conditions, convenient operation, lower toxicity, and wide functional group tolerance.

MATERIALS
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브랜드
제품 설명

Sigma-Aldrich
tert-Butyl isocyanide, 98%