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Merck
  • Catalytic sp3 C-H oxidation of peptides and their analogues by radical cation salts: from glycine amides to quinolines.

Catalytic sp3 C-H oxidation of peptides and their analogues by radical cation salts: from glycine amides to quinolines.

The Journal of organic chemistry (2013-08-21)
Xiaodong Jia, Yaxin Wang, Fangfang Peng, Congde Huo, Liangliang Yu, Jing Liu, Xicun Wang
초록

A catalytic α-sp(3) C-H oxidation of peptides and glycine amides was achieved under radical cation salt catalysis in the presence of O2, producing a series of substituted quinolines. The scope of this reaction shows good functional group tolerance and high efficiency of the oxidative functionalization.

MATERIALS
제품 번호
브랜드
제품 설명

Sigma-Aldrich
Glycinamide hydrochloride, ≥99.0% (AT)
Sigma-Aldrich
Glycinamide hydrochloride, 98%