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Merck
  • Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.

Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.

Chemical communications (Cambridge, England) (2008-03-28)
Jun-Long Zhang, Dewain K Garner, Lei Liang, Qian Chen, Yi Lu
초록

We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity.

MATERIALS
제품 번호
브랜드
제품 설명

Sigma-Aldrich
Thioanisole, ReagentPlus®, ≥99%