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Merck

Color-tunable photoluminescent fullerene nanoparticles.

Advanced materials (Deerfield Beach, Fla.) (2012-03-21)
Jinyoung Jeong, Juyeon Jung, Mijin Choi, Ju Whan Kim, Sang J Chung, Sujin Lim, Han Lee, Bong Hyun Chung
초록

Highly water-soluble and color-tunable photoluminescent fullerene nanoparticles are synthesized by using tetraethylene glycol (TEG) and lithium hydroxide as a catalyst. The maximum PL emission changes depend on the contents of the remaining π-conjugation in oxidized C(60), which is partially covalently conjugated with TEG. The PL behavior is attributed to an electronic transition change due to the distortion of symmetrical C(60).

MATERIALS
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Sigma-Aldrich
Lithium hydroxide, powder, reagent grade, ≥98%
Sigma-Aldrich
Lithium hydroxide, reagent grade, 98%
Sigma-Aldrich
Lithium hydroxide monohydrate, 99.95% trace metals basis
Sigma-Aldrich
Lithium hydroxide monohydrate, BioUltra, ≥99.0% (T)
Sigma-Aldrich
Lithium hydroxide monohydrate, BioXtra, 98.5-101.5% (titration)
Sigma-Aldrich
Lithium hydroxide monohydrate, ACS reagent, ≥98.0%