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Merck
모든 사진(2)

문서

237078

Sigma-Aldrich

Aluminum chloride hexahydrate

ReagentPlus®, 99%

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About This Item

실험식(Hill 표기법):
AlCl3 · 6H2O
CAS Number:
Molecular Weight:
241.43
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.55

vapor pressure

1 mmHg ( 100 °C)

제품 라인

ReagentPlus®

분석

99%

형태

crystalline solid
crystals or chunks

반응 적합성

reagent type: catalyst
core: aluminum

pH

2.5-3.5 (20 °C)

SMILES string

Cl[Al](Cl)Cl.O.O.O.O.O.O

InChI

1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3

InChI key

JGDITNMASUZKPW-UHFFFAOYSA-K

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일반 설명

Aluminum chloride hexahydrate is a nonflammable compound widely employed as a catalyst in organic synthesis. In addition to being extremely soluble in water, it is also soluble in alcohol, ether, glycerol, propylene glycol, and acetonitrile. It has many uses, including the refinement of crude oil, the production of deodorants and antiperspirant products, the dyeing of fabrics, textile finishing.

애플리케이션

Aluminum chloride hexahydrate is used as a catalyst:
  • In the synthesis of corresponding THP (tetrahydropyranylation) ether from alcohol or phenol, and 3,4-dihydro-2H-pyran (DHP).
  • In the direct esterification of levulinic acid and ethanol to produce ethyl levulinate.
  • In the synthesis of gem-dihydroperoxides from ketones and aldehydes.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

Health hazardCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

표적 기관

Lungs

보충제 위험성

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

Ingrid Siemund et al.
Contact dermatitis, 77(5), 288-296 (2017-07-12)
Contact allergy to aluminium has been reported more frequently in recent years. It has been pointed out that positive patch test reactions to aluminium may not be reproducible on retesting. To investigate possible variations in patch test reactivity to aluminium
Mark Baranov et al.
Inorganic chemistry, 58(13), 8877-8883 (2019-06-30)
While sophisticated computational methods can predict 31P NMR spectra of phosphorus atoms encapsulated within Keggin-derived heteropoly tungstate and molybdate cluster anions, calculated and experimental chemical shift values typically deviate considerably from one another. Motivated by the observation that experimentally determined
Aluminium (III) chloride hexahydrate: an efficient and versatile reagent in organic synthesis.
Sarma SD, et al.
ARKIVOC (Gainesville, FL, United States), 1, 243-263 (2013)
[Axillary hyperhydrosis. Local treatment with 25% aluminum chloride hexahydrate in absolute alcohol].
F Brandrup et al.
Ugeskrift for laeger, 140(35), 2106-2109 (1978-08-28)
A neutron and X-ray diffraction investigation of aluminum chloride hexahydrate.
Buchanan DR and Harris PM.
Acta Crystallographica Section B, Structural Science, 24(7), 954-960 (1968)

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