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Merck
모든 사진(1)

문서

31690

Sigma-Aldrich

Diethyl ether

≥99.8% (GC), puriss. p.a., ACS reagent, contains ~0.0005% 2, 6-di-tert-butyl-4-methylphenol as stabilizer

동의어(들):

Et2O, Ethoxyethane, Ether, Ethyl ether

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About This Item

Linear Formula:
(CH3CH2)2O
CAS Number:
Molecular Weight:
74.12
Beilstein:
1696894
EC Number:
MDL number:
UNSPSC 코드:
12352112
PubChem Substance ID:

product name

Diethyl ether, puriss. p.a., ACS reagent, ≥99.8% (GC)

Grade

ACS reagent

vapor density

2.6 (vs air)

grade

puriss. p.a.

분석

≥99.8% (GC)

형태

liquid

autoignition temp.

320 °F

포함

~0.0005% 2,6-di-tert-butyl-4-methylphenol as stabilizer

expl. lim.

36.5 %

불순물

≤0.00003% peroxides (as H2O2)
≤0.0002 meq/g Titr. acid
≤0.0005% free acid (as CH3COOH)
≤0.001% acetaldehyde (CH3CHO)
≤0.001% formaldehyde (HCHO)
≤0.1% water
<0.002% ketone (as CH3COCH3)

증발 잔류물

≤0.001%

refractive index

n20/D 1.3530 (lit.)
n20/D 1.353

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

density

0.706 g/mL at 25 °C (lit.)

양이온 미량물

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

SMILES string

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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일반 설명

Diethyl ether (DEE) is widely employed as solvent for Grignard synthesis. Its efficacy as solvent for Formalin-ether (F-E) sedimentation technique has been studied. It has been reported as a hydroboration solvent. DEE is a promising compression-ignition fuel and its energy density is much higher than ethanol. It is also one of the components in a blend used in diesel fuel.

애플리케이션

Diethyl ether may be employed as solvent for the oxidation of secondary alcohols into ketones. It may be employed as solvent in the preparation of triblock copolymer of PCL-PEG-PCL, acrylated PCL-PEG-PCL and the pentablock copolymer PAE-PCL-PEG-PCL-PAE [PAE = poly(β-amino ester), PEG = poly(ethylene glycol), PCL = poly(ε-caprolactone)].

기타 정보

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.
Sales restrictions may apply

픽토그램

FlameExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

표적 기관

Respiratory system

보충제 위험성

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-40.0 °F - closed cup

Flash Point (°C)

-40 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves


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문서 라이브러리 방문

Dai P Huynh et al.
Biomaterials, 29(16), 2527-2534 (2008-03-11)
The concept of this research is using poly(beta-amino ester) (PAE) as a duo-functional group for synthesis of the novel sensitive injectable hydrogel for controlled drug/protein delivery. Firstly, PAE made of 1,4-butanediol diacrylate and 4,4'-trimethylene dipiperidine is used as a pH-sensitive
Diethyl ether (DEE) as a renewable diesel fuel.
Bailey B, et al.
No. 972978. SAE technical paper (1997)
Oxidation of secondary alcohols in diethyl ether with aqueous chromic acid. Convenient procedure for the preparation of ketones in high epimeric purity.
Brown HC, et al.
The Journal of Organic Chemistry, 36(3), 387-390 (1971)
K H Young et al.
Journal of clinical microbiology, 10(6), 852-853 (1979-12-01)
Ethyl acetate appears to be a satisfactory subsitute solvent for diethyl ether in the Formalin-ether sedimentation technique. In comparative studies, concentration of organisms with ethyl acetate was equal to or greater than that with diethyl ether. No distortion or alteration
Eagleson M.
Concise Encyclopedia Chemistry, 471-471 (1994)

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