sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

GF57012421

Nickel, foil, 50x50mm, thickness 0.3mm, as rolled, 99.999%

GF13066297

Nickel, foil, 25x25mm, thickness 2.0mm, annealed, 99%

GF42729330

Nickel, foil, 10mm disks, thickness 0.025mm, as rolled, 99.99+%

GF84515687

Nickel, tube, 500mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%

GF87059021

Nickel, foil, 25x25mm, thickness 0.125mm, as rolled, 99.999%

GF53673992

Nickel, pellets, 50g, max. size 20mm, 99.99+%

GF16075638

Nickel, foil, 0.5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF31830308

Nickel, microfoil, disks, 25mm, thinness 0.5μm, specific density 438.8μg/cm², permanent mylar 3.5μm support, 99.99+%

GF51837093

Nickel, foil, 50x50mm, thickness 1.0mm, annealed, 99%

GF71874388

Nickel, foil, 2m coil, thickness 0.025mm, coil width 600mm, as rolled, 99%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF05706389

Nickel, foil, 10mm disks, thickness 0.05mm, annealed, 99%

GF68100454

Nickel, wire reel, 10m, diameter 0.125mm, annealed, 99.98%

GF69929274

Nickel, rod, 1000mm, diameter 3.0mm, 99%

GF37939506

Nickel, mesh, 30x30mm, nominal aperture 0.34mm, thickness 0.025mm, wire diameter 0.041mm, 70 wires/inch, open area 80%, electro-formed mesh, 99.9%

GF88557519

Nickel, wire reel, 100m, diameter 0.25mm, hard, 99.98%

GF73152233

Nickel, foil, 0.5m coil, thickness 0.15mm, annealed, 99%

GF18000155

Nickel, foil, 4mm disks, thickness 0.009mm, 99.95%

GF38027998

Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.9%

GF25123159

Nickel, foil, 0.5m coil, thickness 0.0125mm, annealed, 99%

GF91748953

Nickel, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.99+%

GF13212807

Nickel, pellets, 50g, max. size 5mm, 99.99+%

GF70704738

Nickel, wire reel, 10m, diameter 0.125mm, hard, 99.98%

GF69666328

Nickel, rod, 1000mm, diameter 6.35mm, 99%

GF09790869

Nickel, foil, 0.5m coil, thickness 1.0mm, annealed, 99%