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45520

Supelco

Glufosinate-ammonium

PESTANAL®, analytical standard

Synonym(s):

2-Amino-4-(hydroxymethylphosphinyl)butyric acid ammonium salt, DL-Phosphinothricin

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About This Item

Empirical Formula (Hill Notation):
C5H15N2O4P
CAS Number:
77182-82-2
Molecular Weight:
198.16
Beilstein:
8163399
EC Number:
278-636-5
MDL number:
MFCD00055562
UNSPSC Code:
41116107
eCl@ss:
39110524
PubChem Substance ID:
329756807
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

215 °C

application(s)

agriculture
environmental

format

neat

SMILES string

N.CP(O)(=O)CCC(N)C(O)=O

InChI

1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3

InChI key

ZBMRKNMTMPPMMK-UHFFFAOYSA-N

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General description

Glufosinate-ammonium is a phosphinic acid analog of glutamic acid.

Application

Glufosinate-ammonium may be used as a reference standard for the determination of the analyte in:
  • Human serum samples by mixed-mode solid-phase extraction (SPE), tert-butyldimethylsilyl (t-BDMS) derivatization and gas chromatography-mass spectrometry (GC-MS) operating on electron impact (EI) mode of detection.
  • Water samples by ion-exchange cleanup and derivatization followed by analysis using GC coupled to tandem mass spectrometry (MS/MS) equipped with EI mode of detection.
  • Finnish arable soils by high performance liquid chromatography combined with fluorescence detection (HPLC-FLD).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Repr. 1B - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL3906
BCCG6668
BCCD1440
BCBZ5145
BCBT2199

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Ji-Hui Byeon et al.
Biochemical and biophysical research communications, 441(1), 243-248 (2013-10-22)
We present an efficient method for the production of N-acetyl-L-phosphinothricin (N-AcPt) from commercial DL-phosphinothricin (DL-PPT) by organic acetylation for use as a negative selection agent (NSA) that induces cell death in argE transgenic rice. DL-PPT was efficiently converted into N-AcPt
Determination of glufosinate ammonium and its metabolite, 3-methylphosphinicopropionic acid, in human serum by gas chromatography-mass spectrometry following mixed-mode solid-phase extraction and t-BDMS derivatization.
Hori Y, et al.
Journal of Analytical Toxicology, 25(8), 680-684 (2001)
Miao Wang et al.
PloS one, 10(3), e0118476-e0118476 (2015-03-04)
The onset of floral development is a pivotal switch in the life of soybean. Brassinosteroids (BRs), a group of steroidal phytohormones with essential roles in plant growth and development, are associated with flowering induction. Genes involved in BR biosynthesis have
Anna R Snapp et al.
Planta, 240(3), 599-610 (2014-07-16)
Co-expression of a lesquerella fatty acid elongase and the castor fatty acid hydroxylase in camelina results in higher hydroxy fatty acid containing seeds with normal oil content and viability. Producing hydroxy fatty acids (HFA) in oilseed crops has been a
Paola M Peltzer et al.
Ecotoxicology (London, England), 22(7), 1165-1173 (2013-07-23)
In this study, amphibian tadpoles of Hypsiboas pulchellus were exposed to herbicide Liberty®, which contains glufosinate ammonium (GLA), for 48 h to the following concentrations: 0 (control), 3.55, 4.74, 6.32, 8.43, 11.25, 15, 20, 26.6, and 35.5 mg GLA L(-1).
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