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45434

Supelco

Dichlon

PESTANAL®, analytical standard

Synonym(s):

2,3-Dichloro-1,4-naphthoquinone, Dichlon

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About This Item

Empirical Formula (Hill Notation):
C10H4Cl2O2
CAS Number:
Molecular Weight:
227.04
Beilstein:
1073511
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

194-197 °C (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

ClC1=C(Cl)C(=O)c2ccccc2C1=O

InChI

1S/C10H4Cl2O2/c11-7-8(12)10(14)6-4-2-1-3-5(6)9(7)13/h1-4H

InChI key

SVPKNMBRVBMTLB-UHFFFAOYSA-N

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General description

Dichlon is an agricultural fungicide of the quinone class, widely used against a variety of plant pathogenic fungi.

Application

Dichlon may be used as an analytical reference standard for the quantification of the analyte in food matrices using supercritical fluid extraction (SFE) and supercritical fluid chromatography (SFC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Thin-layer chromatography of some substituted naphthoquinones
Agricultural and Biological Chemistry, 30(9), 935-936 (1966)
Pesticide residues in canned foods, fruits, and vegetables: The application of supercritical fluid extraction and chromatographic techniques in the analysis
EL-Saeid.HM
TheScientificWorldJournal, 3(3), 1314-1326 (2003)
Chemistry and Biology of Water, Air and Soil: Environmental Aspects
Studies in Environmental Science, 53(3), 1314-1326 (1993)
H J Kallmayer et al.
Die Pharmazie, 57(8), 530-534 (2002-09-14)
Dialkylamine drugs desipramine, propanolol, pindolol, alprenolol and metoprolol 4a-e react with 2,3-dichloro-1,4-naphthoquinone (2) and acetaldehyde to give red coloured 2-dialkylamino-3-chloro-1,4-naphthoquinones 5a, b, d, e, blue coloured 2-dialkylamino-vinyl-3-chloro-1,4-naphtho-quinones 1a-e and bluish green coloured 2-dialkylamino-butadienyl-3-chloro-1,4-naphthoquinones 6b-e. The colour products are isolated by
C A Pritsos et al.
Biochemical pharmacology, 35(7), 1131-1135 (1986-04-01)
Dietary exposure of rats to a high concentration of 2,3-dichloro-1,4-naphthoquinone (CNQ) (2 g/kg diet) for 60 days altered cardiac mitochondrial function and activities of anti-oxidant enzymes in hepatic and cardiac tissue. CNQ moderately depressed the cardiac mitochondrial respiratory control ratio

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