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A35208

Sigma-Aldrich

Allyl phenyl ether

99%

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About This Item

Linear Formula:
C6H5OCH2CH=CH2
CAS Number:
1746-13-0
Molecular Weight:
134.18
Beilstein:
1905622
EC Number:
217-125-3
MDL number:
MFCD00008644
UNSPSC Code:
12162002
PubChem Substance ID:
24890779
NACRES:
NA.23

Assay

99%

form

liquid

refractive index

n20/D 1.522 (lit.)

bp

192 °C (lit.)

density

0.978 g/mL at 25 °C (lit.)

SMILES string

C=CCOc1ccccc1

InChI

1S/C9H10O/c1-2-8-10-9-6-4-3-5-7-9/h2-7H,1,8H2

InChI key

POSICDHOUBKJKP-UHFFFAOYSA-N

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Related Categories

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

145.4 °F - closed cup

Flash Point(C)

63 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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M Mahmoudian et al.
Applied microbiology and biotechnology, 37(1), 28-31 (1992-04-01)
Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ether. These organisms included Aerococcus, Alcaligenes, Micrococcus and Staphylococcus spp. and
Ralph Moser et al.
Organic letters, 12(1), 28-31 (2009-12-03)
Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.
Anders Dahlén et al.
Organic letters, 5(22), 4085-4088 (2003-10-24)
[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrates.

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