- Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H(2)-Evolution Catalysts.
Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H(2)-Evolution Catalysts.
Journal of the American Chemical Society (2016-12-21)
Noémie Elgrishi, Daniel A Kurtz, Jillian L Dempsey
PMID27997157
要旨
The need for benchmarking hydrogen evolution catalysts has increasingly been recognized. The influence of acid choice on activity is often reduced to the overpotential for catalysis. Through the study of a stable cobalt hydride complex, we demonstrate the influence of acid choice, beyond pK
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