Surface-Coated Thermally Expandable Microspheres with a Composite of Polydisperse Graphene Oxide Sheets.

Surface-modified thermally expandable microcapsules (TEMs) hold potential for applications in various fields. In this work, we discussed the possible surface coating mechanism and reported the properties of TEMs coated with polyaniline (PANI) and polydisperse graphene oxide sheets (ionic liquid-graphene oxide hybrid nanomaterial (ILs-GO)). The surface coating of PANI/ ILs-GO increased the corresponding particle size and its distribution range. The morphologies analyzed by scanning electron microscopy indicated that no interfacial gap was observed between the microspheres ink and substrate layer during the substrate application. The thermal properties were determined by thermogravimetric and differential thermal analyses. The addition of ILs-GO to the polyaniline coating significantly improved the thermal expansion and thermal conductivity of the microcapsules. The evaporation of hexane present in the core of TEMs was not prevented by the coating of PANI/ ILs-GO. The printing application of TEMs showed excellent adaptability to various flexible substrates with great 3D appearance. By incorporating a flame retardant agent into TEMs coated by PANI/ILs-GO, finally, these TEMs also demonstrated a great flame retardant ability. We expect that these TEM-coated PANI/ ILs-GO are likely to have the potential to improve the functional properties for various applications.