Oxidative cleavage of allyl ethers by an oxoammonium salt.

Oxidative cleavage of allyl ethers by an oxoammonium salt.

Organic & biomolecular chemistry (2015-03-10)

Christopher B Kelly, John M Ovian, Robin M Cywar, Taylor R Gosselin, Rebecca J Wiles, Nicholas E Leadbeater

要旨

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

材料

製品番号

ブランド

製品内容

745537

Sigma-Aldrich

4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate, 97% (HPLC)