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  • Time-lapse 3D imaging by positron emission tomography of Cu mobilized in a soil column by the herbicide MCPA.

Time-lapse 3D imaging by positron emission tomography of Cu mobilized in a soil column by the herbicide MCPA.

Scientific reports (2018-05-08)
Johannes Kulenkampff, Madeleine Stoll, Marion Gründig, Alexander Mansel, Johanna Lippmann-Pipke, Michael Kersten
要旨

Phenoxyalkanoic acids like the 4-chloro-2-methylphenoxyacetic acid (MCPA) are the second highest used xenobiotic herbicides worldwide after glyphosate because of their apparently favorable environmental properties. Experimental batch equilibration data suggested a reduced Cu adsorption efficiency with the soil mineral goethite below pH 6 in presence of MCPA. This has been verified by advanced surface complexation adsorption modelling involving dissolved Cu-MCPA complexation constants. Positron emission tomography is a non-invasive molecular imaging method for time-resolved three-dimensional information commonly applied on non-retarded tracers in soil core scale experiments. Mineral surface reactive tracers like Cu-64 are too immobile for the relatively short observation times available with this advanced imaging technique. However, Cu-64 radiolabeled Cu-MCPA complex migration could be observed in as long as 10-cm artificial soil test columns where break-through occurred within a few days. For the first time, time-lapse movies of Cu migration in the opaque soil columns were recorded using this novel reactive transport process tomography approach.

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Sigma-Aldrich
針鉄鉱, 30-63% Fe