439169

酢酸エチル

suitable for HPLC, ≥99.8%

• 別名: EtOAc
• 化学式: CH₃COOC₂H₅
• CAS番号: 141-78-6
• 分子量: 88.11
• Beilstein: 506104
• EC Number: 205-500-4
• MDL番号: MFCD00009171
• UNSPSCコード: 12190000
• PubChem Substance ID: 329756423
• NACRES: NA.21

特性

• 蒸気密度: 3 (20 °C, vs air)
• 品質水準: 100
• 蒸気圧: 73 mmHg ( 20 °C)
• アッセイ: ≥99.8%
• 形状: liquid
• 自己発火温度: 801 °F
• expl. lim.: 2.2-11.5 %, 38 °F
• テクニック: GC/MS: suitable; HPLC: suitable
• 不純物: <0.050% water
• 蒸発残留物質: <0.0003%
• 屈折率: n20/D 1.3720 (lit.)
• bp: 76.5-77.5 °C (lit.)
• mp: −84 °C (lit.)
• 溶解性: alcohol: soluble(lit.); chloroform: soluble(lit.)
• 密度: 0.902 g/mL at 25 °C (lit.)
• λ: H₂O reference
• UV吸収: λ: 254 nm A_max: 1.00; λ: 263 nm A_max: 0.05; λ: 275-400 nm A_max: 0.01
• アプリケーション: food and beverages
• フォーマット: neat
• SMILES記法: CCOC(C)=O
• InChI: 1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3
• InChI Key: XEKOWRVHYACXOJ-UHFFFAOYSA-N

詳細

詳細

Ethyl acetate (EA), a carboxylate ester, is bio-friendly organic solvent with a wide range of industrial applications. Its synthesis by reactive distillation and by acceptorless dehydrogenative dimerization of ethanol has been explored. Its ability as an acyl acceptor in the immobilized lipase-mediated preparation of biodiesel from crude vegetable oils has been examined. The complete degradation of ethyl acetate to CO₂ using manganese octahedral molecular sieve (OMS-2) has been investigated. EA is an effective alternate solvent of diethyl ether, employed for the concentration of eggs, larvae, and cysts in fecal specimens during the Formalin-ether sedimentation technique. Acetaldehyde is reaction intermediate formed during the oxidative combustion of ethanol and ethyl acetate in the presence of copper oxide embedded on Ce-doped titania surface.

アプリケーション

Ethyl acetate may be used in the following studies:

• As solvent for the isolation of Rose hip (Rosa canina L., Rosaceae) powder, via sonication.
• As solvent for the abstraction of volatile thiols from wine for their quantitative estimation by gas chromatography/mass spectrometry (GC-MS).
• Preparation of thin films of TiO₂ (titanium dioxide) on glass.
• As an extraction medium in the multi-residue analysis of pesticide residues in fruit and vegetables.
• Acetylation of primary amines to form amides in the presence of dimethyltin(IV) acetic acid distannoxane.

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安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H319,H336
• 注意書き: P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• ターゲットの組織: Central nervous system
• 補足的ハザード: EUH066
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): 24.8 °F - closed cup
• 引火点(℃): -4 °C - closed cup