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Merck

Process development for scum to biodiesel conversion.

Bioresource technology (2015-03-17)
Chong-hao Bi, Min Min, Yong Nie, Qing-long Xie, Qian Lu, Xiang-yuan Deng, Erik Anderson, Dong Li, Paul Chen, Roger Ruan
ABSTRACT

A novel process was developed for converting scum, a waste material from wastewater treatment facilities, to biodiesel. Scum is an oily waste that was skimmed from the surface of primary and secondary settling tanks in wastewater treatment plants. Currently scum is treated either by anaerobic digestion or landfilling which raised several environmental issues. The newly developed process used a six-step method to convert scum to biodiesel, a higher value product. A combination of acid washing and acid catalyzed esterification was developed to remove soap and impurities while converting free fatty acids to methyl esters. A glycerol washing was used to facilitate the separation of biodiesel and glycerin after base catalyzed transesterification. As a result, 70% of dried and filtered scum was converted to biodiesel which is equivalent to about 134,000 gallon biodiesel per year for the Saint Paul waste water treatment plant in Minnesota.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Methanol, suitable for HPLC
Sigma-Aldrich
Diethyl ether, for residue analysis, JIS 5000
Sigma-Aldrich
Sulfuric acid solution, 0.1 M
Sigma-Aldrich
Sulfuric acid solution, 0.05 M
Sigma-Aldrich
Sodium hydroxide solution, 0.05 M
Sigma-Aldrich
Hydrochloric acid solution, 0.1 M
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Sulfuric acid solution, 5 mM
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Sodium hydroxide solution, 6 M
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Hydrochloric acid solution, SAJ first grade, 9.5-10.0%
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Hydrochloric acid solution, 0.2 M
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Sulfuric acid solution, 0.025 M
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Sulfuric acid, ≥97.0%, suitable for determination of toxic metals
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Methanol, SAJ first grade, ≥99.5%
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Sulfuric acid solution, SAJ first grade, 32.2-36.8% in H2O
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Hydrogen chloride – ethanol solution, 0.1 M in ethanol
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Hydrochloric acid, SAJ first grade, 35.0-37.0%
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Hydrogen chloride – ethanol solution, 3% in ethanol
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Hydrochloric acid solution, 0.02 M
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Methanol, JIS 300, ≥99.8%, for residue analysis
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Hydrochloric acid, suitable for determination of toxic metals, ≥35.0%
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Sodium hydroxide solution, 0.5 M
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Sulfuric acid, ≥97.0%, SAJ super special grade
Sigma-Aldrich
Hydrochloric acid, suitable for arsenic determination, 35.0-37.0%
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Sodium hydroxide solution, 2 M
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Chloroform, SAJ first grade, ≥99.0%, contains 0.4-0.8% ethanol
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Chloroform, JIS 300, ≥99.0%, for residue analysis
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Sodium hydroxide solution, 0.02 M
Sigma-Aldrich
Hydrochloric acid solution, 0.05 M
Sigma-Aldrich
Hydrochloric acid solution, 2 M
Sigma-Aldrich
Ethanol, JIS special grade, 94.8-95.8%